How to Interpret the Mass Spectrum of a Straight-chain Saturated Hydrocarbon
Early in MS most of the work was focused on hydrocarbons of interest to the petroleum industry.
Recognize the spectral pattern in the gas chromatography-mass spectrometry (GC-MS) electron ionization (EI) of an unbranched alkane, viz., Dodecane! The image is self-explanatory (hope so).
Click to enlarge the image
M = Molecular, EE = Even-electron, OE = Odd-electron, BE = Bond energy
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References:
(1) Wikipedia Contributors. Gas chromatography–mass spectrometry. Wikipedia. https://en.wikipedia.org/wiki/Gas_chromatography%E2%80%93mass_spectrometry.
(2) SDBS, Spectral Database for Organic Compounds, AIST. sdbs.db.aist.go.jp. https://sdbs.db.aist.go.jp/.