How to Calculate the Enthalpy of Combustion of a Molecule – Part 1
The enthalpy of combustion of a substance, usually a fuel/food, is the amount of enthalpy/heat/energy released (in calorie/Joule) during the combustion/burning of a given amount of it.
The enthalpy of combustion always
has a negative value (exothermic reaction).
Question:
2CH6N2(l) + 5O2(g)
→ 2N2(g) + 2CO2(g) + 6H2O(g)
The combustion of Methylhydrazine, a common
rocket fuel, is represented above. ΔHr = –1303 kJ mol−1.
What would be the ΔH per mol of CH6N2(l)
if the reaction produced H2O(l) instead of H2O(g)?
(ΔH for the condensation of H2O(g) to H2O(l)
= –44 kJ mol−1)
Solution:
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References:
(1) Wikipedia Contributors. Heat of combustion. Wikipedia. https://en.wikipedia.org/wiki/Heat_of_combustion.
(2) Ncert. Chemistry : Textbook for Class XI - Part.I; National Council Of Educational Research And Training: New Delhi.