How to Understand the Relation between the Optical Rotation and the Absolute Configuration

It may sometimes look like there exists a correlation between the optical rotation & the absolute configuration.


However, the optical rotation is NOT directly related to the absolute configuration.



Click/tap to enlarge the image

SN2 = Substitution nucleophilic bimolecular

Does it make sense❓ Let Chemaficionado know in the comments below or at mychemistryhomework@gmail.com❗

References:

(1)    Wikipedia Contributors. Cahn–Ingold–Prelog priority rules. Wikipedia. https://en.wikipedia.org/wiki/Cahn%E2%80%93Ingold%E2%80%93Prelog_priority_rule

s.

(2) Chouhan, M. S. Advanced Problems in Organic Chemistry for JEE, 11th Ed.

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