How to Face an Organic Reaction Involving an Oxidizing Agent – Part 2

An inorganic compound can work as an oxidizing agent for an organic compound.


Depending on the substrate, an oxidant may produce an alcohol/aldehyde/epoxide, a carboxylic acid/diol/ketone, among many others. Chemoselectivity and stereochemistry are observed as well.

Question:

Predict the major product(s) of the following reactions:



Click/tap to enlarge the image

Solution infographic:



Click/tap to enlarge the image

Ominous oxidizing agent❓ Let Chemaficionado know in the comments below or at mychemistryhomework@gmail.com❗

References:

(1)    Chouhan, M. S. Advanced Problems in Organic Chemistry for JEE, 11th Ed.

(2)    Ncert. Chemistry : Textbook for Class XI - Part.II; National Council Of Educational Research And Training: New Delhi.

(3)    Graham, T. W.; Fryhle, C. B.; Snyder, S. A. Organic Chemistry.; Hoboken, Nj John Wiley Et Sons, Inc, 2016.

(4)    Lemieux, R. U.; Rudloff, E. Von. Periodate–Permanganate Oxidations: I. Oxidation of Olefins. Canadian Journal of Chemistry 1955, 33 (11), 1701–1709. https://doi.org/10.1139/v55-208.

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